Drinking water is a fundamental necessity for life, and we often take for granted the clean, safe water that flows from our taps. But have you ever wondered how this water becomes safe to drink? One critical ingredient in this process is chlorine, a disinfection chemical. However, recent concerns have arisen about the effectiveness of chlorine in dealing with specific waterborne pathogens and its potential health risks. This concern has sparked the exploration of alternative methods for treating our drinking water.
The Role of Chlorine in Water Treatment: Pros and Cons
For years, chlorine has been the go-to choice for disinfecting drinking water. As a powerful disinfectant, it kills microorganisms in drinking water, preventing diseases like cholera, typhoid fever, dysentery, and hepatitis A. Additionally, chlorine helps reduce unpleasant tastes and odours, eliminates slime bacteria, moulds, and algae, and removes iron and manganese from raw water.
However, chlorine has its drawbacks. as the world is changing, and new challenges are emerging. One of these challenges is the increased presence of waterborne pathogens like Giardia and Cryptosporidium. While chlorine has been moderately effective against some of these pathogens, it’s been less effective against others, such as Cryptosporidium. One significant issue is that it reacts with organic compounds naturally found in water, creating DBPs, such as trihalomethanes and haloacetic acids. Some DBPs have been associated with increased risks of certain cancers and adverse effects on various body systems. Furthermore, chlorine can irritate sensitive individuals’ eyes, skin, and respiratory tract. It can also corrode pipes and fixtures, potentially damaging leaks and water.
Balancing the benefits and risks of using chlorine in water treatment is essential. Properly monitoring chlorine and DBP levels in drinking water is crucial to maintaining safe and healthy water quality.
Exploring Alternatives to Chlorine
The quest for alternatives to chlorine in water treatment has led to the investigating of various methods, each with its advantages and disadvantages. Some other options include bromine, ozone, ultraviolet (UV) radiation, and chlorine dioxide.
Bromine: Similar to chlorine, bromine is a chemical element with disinfection properties, but it remains stable in hot water and is less affected by pH changes. While bromine can react with organic matter to form DBPs, they are generally less harmful than those created by chlorine. However, bromine is costlier than chlorine and can cause skin and eye irritation and metal corrosion.
Ozone: Ozone, a gas produced by passing oxygen through an electric discharge or UV radiation, is a potent oxidant and disinfectant. It can destroy microorganisms, organic compounds, iron, manganese, and hydrogen sulphide in water. Ozone improves water taste and odour and leaves no residual disinfectant behind. Nevertheless, ozone’s instability requires on-site generation, incurring high capital and operating costs. Additionally, it can form carcinogenic DBPs called bromates in the presence of bromide in the water.
Ultraviolet (UV) Light: UV light is a form of electromagnetic radiation that inactivates microorganisms by damaging their DNA. UV treatment does not alter water’s chemical composition and produces no DBPs or residual disinfectant. However, UV light is most effective with clear water and requires substantial energy input.
Chlorine Dioxide: Chlorine dioxide, generated by mixing sodium chlorite with an acid or chlorine, is a selective oxidant and disinfectant that can kill microorganisms, oxidize iron and manganese, and control taste and odour. Chlorine dioxide also reduces the formation of DBPs like trihalomethanes and haloacetic acids. Nevertheless, its instability necessitates on-site production, which poses safety and operational challenges. Chlorine dioxide can also form chlorite and chlorate, two DBPs that may impact blood cells and thyroid function.
Non-Chemical Alternatives: Membrane and UV Radiation Technologies
Non-chemical alternatives to traditional disinfection methods have also been explored. Two prominent options are membrane processes and UV radiation technologies.
Membrane Processes: Membrane technology employs thin, porous sheets to separate contaminants from water. These membranes come in various types, including microfiltration, ultrafiltration, nanofiltration, and reverse osmosis. Depending on the type, membrane processes can remove suspended solids, bacteria, viruses, organic compounds, dissolved salts, metals, and more. They offer high efficiency, low energy consumption, and minimal chemical use. However, they also come with challenges such as high costs, maintenance needs, fouling, scaling, and concentrate disposal.

UV Radiation Technology: UV light inactivates microorganisms by damaging their DNA without altering water chemistry or producing DBPs. It doesn’t provide residual disinfection and is most effective with clear water, but requires significant energy input.
The European Approach: Multiple Barriers and Biological Treatment
In some northern European countries, a different approach has been taken. Instead of relying heavily on chemical disinfection, they have adopted a strategy including multiple barriers, such as natural and biological treatment stages. These barriers are designed to prevent contamination and remove or inactivate microorganisms.
This approach, while effective, requires an in-depth understanding of the local area and water sources. Selecting the best location where natural systems can work optimally with current technology is crucial.
The Dutch Success Story
One notable success story in moving away from chlorine-based disinfection is the Netherlands. They ceased using chlorine as a disinfectant for drinking water in 2005. This achievement demonstrates that it’s possible to successfully transition away from traditional methods with careful planning and the right combination of alternative technologies.
The Dutch success story is a testament to innovative water management practices. In the Netherlands, water boards, institutions responsible for managing water quantity and quality, have a rich history dating back to the Middle Ages. They collaborate with residents, businesses, and organizations to ensure adequate water management and pollution control. Moreover, the Dutch have pioneered advanced technologies for wastewater treatment, such as aerobic granular sludge technology.
The Dutch culture emphasizes water awareness, cooperation, and the importance of water management. They actively share their knowledge and expertise with the world through participation in international water projects and initiatives.
Ensuring the safety of our drinking water is of paramount importance. While chlorine has long been a reliable disinfectant, emerging challenges and health concerns have prompted the exploration of alternative methods. These alternatives promise clean, safe water without some of the drawbacks of chlorine. Whether through chemical options, non-chemical methods, or innovative approaches like those in the Netherlands, the quest for safe drinking water continues to evolve and improve.
References:
- Alternatives to Chlorine as a Disinfectant in Drinking Water Retrieved September 22, 2023 from environbuzz.com/alternatives-to-chlorine-as-a-disinfectant-in-drinking-water/
- Alternatives to Chemical Disinfection of Drinking Water. Retrieved Oct 3, 2017 – http://www.fwr.org/waterq/dwi0808.htm
- Chlorine Substitutes In Water May Have Risks Retrieved Oct 3, 2017 –http://www.npr.org/2011/01/07/132743638/disinfectant-to-clean-water-has-problems-of-its-own
- A Water Treatment Alternative to Chlorine? Retrieved Oct 3, 2017 – http://insights.globalspec.com/article/3112/a-water-treatment-alternative-to-chlorine
- Chlorine and Alternative Disinfectants Guidance Manual Retrieved Oct 3, 2017 Prepared for Office of Drinking Water Prepared by Earth Tech (Canada) Inc. Mar, 2005 https://www.google.ca/url?sa=t&rct=j&q=&esrc=s&source=web&cd=16&cad=rja&uact=8&ved=0ahUKEwir5aaylNXWAhUJzIMKHfK8DWQQFghwMA8&url=https%3A%2F%2Fwww.gov.mb.ca%2Fwaterstewardship%2Fodw%2Freg-info%2Fapprovals%2Fodw_chlorine_and_alternative_disinfectants.pdf&usg=AOvVaw3Wn0gIEQh7nL-FlqtVX2j1
- The medieval Dutch solution to flooding – BBC Future retrieved on September 22, 2023 from bbc.com/future/article/20211129-the-medieval-dutch-solution-to-flooding
- Dutch Scientist Develops New Way to Turn Sludge into Drinking Water (nextcity.org) retrieved on September 22, 2023 from nextcity.org/urbanist-news/netherlands-wastewater-treatment-nereda
- Water supply and sanitation in the Netherlands – Wikipedia retrieved on September 22, 2023 from en.wikipedia.org/wiki/Water_supply_and_sanitation_in_the_Netherlands
- Assuring water quality along multi-barrier treatment systems for agricultural water reuse | Journal of Water Reuse and Desalination | IWA Publishing (iwaponline.com) retrieved on September 22, 2023 from iwaponline.com/jwrd/article/10/4/332/76804/Assuring-water-quality-along-multi-barrier
- Chapter 3: A Multi-Barrier Approach to Drinking Water Safety retrieved on September 22, 2023 from archives.gov.on.ca/en/e_records/walkerton/report2/pdf/Chapter_3.pdf
- Water treatment processes Retrieved on September 22, 2023 from cdn.dwi.gov.uk/wp-content/uploads/2020/11/25104815/Treatment-processes.pdf
- The Dutch secret: how to provide safe drinking water without chlorine in the Netherlands Retrieved on September 22, 2023 from dwes.copernicus.org/articles/2/1/2009/dwes-2-1-2009.pdf
- Assuring water quality along multi-barrier treatment systems for agricultural water reuse Retrieved on September 22, 2023 from iwaponline.com/jwrd/article/10/4/332/76804/Assuring-water-quality-along-multi-barrier
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